Research Publications

278.听鈥淪ynthesis of听Z-gem-Cl,CF3-Substituted Alkenes by Stereoselective Cross-Metathesis and the Role of Disubstituted Mo Alkylidenes鈥澨齉. Liu, C. Qin, J. Wan, B. K. Mai, X. Z. Sui, H. Kobayashi, H. Zahedian, P. Liu, A. H. Hoveyda听

277.听鈥淎 catalytic process enables efficient and programmable access to precisely altered indole alkaloid scaffolds鈥澨齓. Huang, X. Li, B. K. Mai, E. J. Tonogai, A. J. Smith, P. J. Hergenrother, P. Liu, A. H. Hoveyda听

276.听鈥淐lick processes orthogonal to CuAAC and SuFEx forge selectively modifiable fluorescent linkers鈥澨齈. H. S. Paioti, K. E. Lounsbury, F. Romiti, M. Formica, V. Bauer, C. Zandonella, M. E. Hackey, J. del Pozo, A. H. Hoveyda听

275.听鈥淐atalytic Cross-Metathesis Reactions That Afford听E鈥 and听Z鈥慣risubstituted Alkenyl Bromides: Scope, Applications, and Mechanistic Insights鈥澨齌. Koengeter, C. Qin, B. K. Mai, Q. Liu, Y. Mu, P. Liu, A. H. Hoveyda听

274.听鈥Z-Trisubstituted 伪,尾-Unsaturated Esters and Acid Fluorides through Stereocontrolled Catalytic Cross-Metathesis鈥澨鼵. Qin, T. Koengeter, F. Zhao, Y. Mu, F. Liu, K. N. Houk, A. H. Hoveyda听

273.听鈥淒iastereo- and enantioselective synthesis of compounds with a trifluoromethyl- and fluoro-substituted carbon centre鈥澨齋. Xu, J. del Pozo, F. Romiti, Y. Fu, B. K. Mai, R. J. Morrison, K. Lee, S. Hu, M. J. Koh, J. Lee, X. Li, P. Liu,听A. H. Hoveyda听

272.听鈥E-听and听Z-trisubstituted macrocyclic alkenes for natural product synthesis and skeletal editing鈥澨齓. Mu, F. W. W. Hartrampf, E. C. Yu, K. E. Lounsbury, R. R. Schrock,听F. Romiti,听A. H. Hoveyda听

271.听鈥淪tereodefined Alkenes with a Fluoro-chloro Terminus as a Uniquely Enabling Compound Class鈥澨齉. Liu, Y. Mu, T. Koengeter,听R. R. Schrock,听A. H. Hoveyda听

270.听鈥淐ross-metathesis of Allenes. Mechanistic Analysis and Identification of a Ru-CAAC as the Most Effective Catalyst鈥澨齋. A. Gonsales, Z. C. Mueller, F. Zhao, P. H. S. Paioti, L. Karmazin, J.听Wan, F. Liu, K. N. Houk,听A. H. Hoveyda听

269.听鈥淥xo 2-Adamantylidene Complexes of Mo(VI) and W(VI)鈥澨齅. Boudjelel, F. Zhai,听R. R. Schrock,听A. H. Hoveyda,听C. Tsay

268.听鈥淏oosting the Metathesis Activity of Molybdenum Oxo Alkylidenes by Tuning the Anionic Ligand 蟽 Donation鈥澨齁. De Jesus Silva, M. Pucino, F. Zhai, D. Mance, Z. J. Berkson, D. F. Nater, A. H. Hoveyda, C.听Cop茅ret,听R. R. Schrock听

267.听鈥淪treamlined Catalytic Enantioselective Synthesis of 伪-Substituted 尾,纬-Unsaturated Ketones and Either of the Corresponding Tertiary Homoallylic Alcohol Diastereomers鈥澨齁. del Pozo, S. Zhang, F. Romiti, S. Xu, R. P. Conger, A. H. Hoveyda听听

266.听鈥淪yntheses of 鈥淧hosphine-Free鈥 Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes鈥澨 F. Zhai, R. R. Schrock,听A. H. Hoveyda, P.听M眉ller听

265.听鈥淪ulfonate N鈥怘eterocyclic Carbene鈥揅opper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C鈭扖, C鈭払, C鈭扝, and C鈭扴i Bonds鈥澨 A.听H. Hoveyda, Y. Zhou, Y. Shi, M. K. Brown, H. Wu, S. Torker听

264.听鈥淩egio鈥 and Enantioselective Synthesis of Trifluoromethyl鈥怱ubstituted Homoallylic 伪鈥怲ertiary NH2鈥怉mines by Reactions Facilitated by a Threonine鈥怋ased Boron鈥怌ontaining Catalyst鈥澨 D. C. Fager, R. J. Morrison,听A. H. Hoveyda听听

263.听鈥淎 Catalytic Approach for Enantioselective Synthesis of Homoallylic Alcohols Bearing听听Z-Alkenyl Chloride or Trifluoromethyl Group. A Protecting Group-Free Synthesis of Mycothiazole鈥澨 R. J. Morrison, F. W. van der Mei, F. Romiti,听A. H. Hoveyda听听

262.听鈥淐atalytic Enantioselective Conjugate Addition of Stereodefined Di- and Trisubstituted Alkenylaluminum Compounds to Acyclic Enones鈥澨齂. P. McGrath, A. K. Hubbell, Y. Zhou, D. P.Santos, S. Torker, F. Romiti, A. H. Hoveyda听听

261.听鈥淐atalytic Enantioselective Boryl and Silyl Substitution with Trifluoromethyl Alkenes: Scope, Utility, and Mechanistic Nuances of Cu鈭扚 尾鈥慐limination鈥澨齈. H. S. Paioti, J. del Pozo, M. S. Mikus, J. Lee, M. J. Koh, F. Romiti, S. Torker, A. H. Hoveyda听

260.听鈥淐atalytic Enantioselective Addition of an Allyl Group to Ketones Containing a Tri-, a Di-, or a Monohalomethyl Moiety. Stereochemical Control Based on Distinctive Electronic and Steric Attributes of C鈥揅l, C鈥揃r, and C鈥揊 Bonds鈥 D. C. Fager, K. Lee, A. H. Hoveyda听

259.听鈥淐opper鈥揌ydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis鈥 Y. Sun, Y. Zhou, Y. Shi, J. del Pozo, S. Torker, A. H. Hoveyda听

258.听鈥淐atalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F-Substituted Stereogenic Quaternary Center鈥 S. Akiyama, K. Kubota, M. S. Mikus, P. H. S. Paioti, F. Romiti, Q. Liu, Y. Zhou, A. H. Hoveyda, H. Ito听

257.听鈥淪ilica鈥怱upported Molybdenum鈥怬xo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis鈥 M. Pucino, F. Zhai, C. P. Gordon, D. Mance, A. H. Hoveyda, R. R. Schrock, C. Cop茅ret听

256.听鈥淩u-Based Catechothiolate Complexes Bearing an Unstaturated NHC Ligand: Effective Cross-Metathesis Catalysts for Synthesis of (Z)-伪,尾-Unsaturated Esters, Caboxylic Acids and Primary, Secondary, and Weinreb Amides鈥 Z. Liu, C. Xu, J. del Pozo, S. Torker, A. H. Hoveyda听

255.听E鈥 and听Z-, Di- and Tri-Substituted Alkenyl Nitriles Through Catalytic Cross-Metathesis鈥 Y. Mu, T. Nguyen, M.J. Koh, R. R. Schrock, A. H. Hoveyda听

254.听鈥淒elayed Catalyst Function Enables Direct Enantioselective Conversion of Nitriles to NH2-Amines鈥 S. Zhang, J. del Pozo, F. Romiti, Y. Mu, S. Torker, A. H. Hoveyda听

253.听鈥淭raceless Protection for More Broadly Applicable Olefin Metathesis鈥 Y. Mu, T. Nguyen, F. W. van der Mei, R. R. Schrock, A. H. Hoveyda听

252.听鈥淩acemic Vinylallenes in Catalytic Enantioselective Mutlicomponent Processes. Rapid Generation of Complexity through 1,6-Conjugate Additions鈥 Y. Huang, S. Torker, X. Li, J. del Pozo, A. H. Hoveyda听

251.听鈥淪N2鈥-Selective and Enantioselective Substitution with Unsaturated Organoboron Compounds and Catalyzed by a Sulfonate-Containing NHC-Cu Complex鈥 Y. Zhou, Y. Shi, S. Torker, and A. H. Hoveyda 听.

250.听鈥淪yntheses of Molybendenum Oxo Benzylidene Complexes鈥 F. Zhai, K. V. Bukhryakov, R.R. Schrock, A. H. Hoveyda, C. Tsay, P. M眉ller 听

249.听鈥溛-, Diastereo-, and Enantioselective Addition of MEMO-Substituted Allylboron Compounds to Aldimines Catalyzed by Organoboron-Ammonium Complexes鈥 R. J. Morrison,听 A. H. Hoveyda听

248.听鈥淪yntheses of High-Oxidation-State Mo鈺怌HX Complexes, Where X = Cl, CF3, Phosphonium, CN鈥 S. VenkatRamani, R.R. Schrock, A. H. Hoveyda, P. M眉ller, C. Tsay 听

247.听鈥淪yntheses of Molybendenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex鈥 K. V. Bukhryakov, R.R. Schrock, A. H. Hoveyda, C. Tsay, P. M眉ller 听

246.听鈥淓nantioselective Synthesis for Trisubstituted Allenyl鈥擝(pin) Compounds by Phosphine鈥擟u-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Intergrity of Cu鈥擜llenyl Intermediates鈥 Y. Huang, J. del Pozo, S. Torker, A. H. Hoveyda 听

245.听鈥淢echanism-based Enhancement of Scope and Enantioselectivity for Reactions Involving a Copper-Substituted Stereogenic Carbon Centre鈥 J. Lee, S. Radomkit, S. Torker, J. del Pozo, A. H. Hoveyda 听

244.听鈥淪ynthesis of听E-and听Z-Trisubstituted Alkenes by Catalytic Cross-Metathesis鈥 T. T. Nguyen, M. J. Koh, T. J. Mann, R. R. Schrock, A. H. Hoveyda 听

243.听鈥淪ynthesis of听Z鈥 or听E-Trisubstituted Allylic Alcohols and Ethers by Kinetically Controlled Cross-Metathesis with a Ru Catechothiolate Complex鈥 C. Xu, Z. Liu, S. Torker, X. Shen, D. Xu, A.H. Hoveyda 听

242.听鈥淪ynthesis of Molybdenum Adamantylimido and听t-Butylimido Alkylidene Chloride Complexes Using HCl and Diphenylmenthylphosphine鈥澨K. V. Bukhryakov, S. VenkatRamani, C. Tsay, A. Hoveyda, R. R. Schrock听

241.听鈥淓nantioselective Total Synthesis of (鈥)-Deoxoapodine鈥 T. Kang, K. L. White, T. J. Mann, A. H. Hoveyda, M. Movassaghi听

240.听鈥淚n Situ Methylene Capping: A General Strategy for Efficient Stereoretentive Catalytic Olefin Metathesis. The Concept, Methodological Implications, and Applications to Synthesis of Biologically Active Compounds鈥澨C. Xu, X. Shen, A. H. Hoveyda听

239.听鈥淐atalytic Diastereo- and Enantioselective Additions of Versatile Allyl Groups to N-H Ketimines,听H. Jang, F. Romiti, S. Torker, A. H. Hoveyda听.

238.听鈥淧ractical, Broadly Applicable, 伪-听Selective,听Z-Selective, Diastereoselective and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri- and Polyfluoroalkyl Ketones,听F. W. van der Mei, C. Qin, R. J. Morrison, A. H. Hoveyda听

237.听鈥淧ractical, Efficient, and Broadly Applicable Synthesis of Readily Differentiable Vicinal Diboronate Compounds by Catalytic Three-Component Reactions,听S. Radomkit, Z. Liu, A. Closs, M.S. Mikus, A. H. Hoveyda. (Special issue in honor of Professor Ben Feringa)

236.听鈥淓lectronically Activated Organoboron Catalysts for Enantioselective Propargyl Addition to Trifluoromethyl Ketones,听N.W. Mszar, M. S. Mikus, S. Torker, F. Haeffner, A. H. Hoveyda听

235.听鈥淪ynthesis of 2,6,-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X + I, Li, OH, SH, N3, or NH2,听K.V. Bukhryakov, R. R. Schrock, A. H. Hoveyda, P. M眉ller, J. Becker听

234.听鈥淢olybdenum Chloride Catalysts for听Z-Selective Olefin Metathesis Reactions,听M. J. Koh, T. T. Nguyen, J. K. Lam, S. Torker, J. Hyvl, R. R. Schrock, A. H. Hoveyda听

233.听鈥淜inetically听E-Selective Macrocyclic Ring-Closing Metathesis,听X. Shen, T. T. Nguyen, M. J. Koh, D. Xu, A. W. H. Speed, R. R. Schrock, A. H. Hoveyda听

232.听鈥淰ersatile Homoallylic Boronates by Chemo-, SN2鈥-, Diastereo- and Enantioslective Catalytic Sequence of Cu鈥擧 Addition to Vinyl-B(pin)/Allylic Substitution,鈥 J. Lee, S. Torker, A. H. Hoveyda听

231.听鈥淪ynthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for听Z-Selective Cross-Metathesis of Cyclooctene and听Z-1,2-Dichloroethylene,鈥 J. Lam, C. Zhu, K. V. Bukhryakov, P. M眉ller, A. H. Hoveyda, R. R. Schrock听.

230.听鈥淧entacoordinate Ruthenium(ll) Catecholthiolate and Mercaptophenolate Catalysts for Olefin Metathesis: Anionic Ligand Exchange and Ease of Initiation,鈥 M. S. Mikus, S. Torker, C. Xu, B. Li, A. H. Hoveyda听.

229.听鈥淪ynthesis of Linear (Z)- 伪 , 尾 -Unsaturated Esters by Catalytic Crosss-Metathesis. The Influence of Acetonitrile,鈥 E. C. Yu, B. M. Johnson, E. M. Townsend, R. R. Schrock, A. H. Hoveyda听

228.听鈥淐atalytic Enantioselective 1,6-Conjugate Additions of Propargyl and Allyl Groups,鈥 F. Meng, X. Li, S. Torker, Y. Shi, X. Shen, A. H. Hoveyda听

227.听鈥淐atalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene,鈥 X. Li, F. Meng, S. Torker, Y. Shi, A. H. Hoveyda听.

226.听鈥淧ractical and Broadly Applicable Catalytic Enantioselective Additions of Allyl鈥揃(pin) Compounds to Ketones and 伪 -Ketoesters,鈥 D. W. Robbins, K. Lee, D. L. Silverio, A. Volkov, S. Torker, A. H. Hoveyda听

225.听鈥淐atalytic Enantioselective Addition of Organoboron Reagents to Fluoroketones Controlled by Electrostatic Interactions,鈥 K. Lee, D. L. Silverio, S. Torker, F. Haeffner, D. W. Robbins, F. W. van der Mei, A. H. Hoveyda听

224.听鈥淜inetically controlled听E-Selective Catalytic Olefin Metathesis,鈥 T. T. Nguyen, M. J. Koh, X. Shen, F. Romiti, R. R. Schrock, A. H. Hoveyda听.

223.听鈥淐ontrollable ROMP Tacticity by Harnessing the Fluxionality of Stereogenic-at-Ruthenium Complexes,听M. S. Mikus, S. Torker, A. H. Hoveyda听.

222.听鈥淟ewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective 纬-Additions of Allylboron Moieties to Aldimines,鈥 F. W. van der Mei, H. Miyamoto, D. L. Silverio, A. H. Hoveyda听.

221.听鈥淐atalytic SN2鈥- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis,鈥 Y. Shi, A. H. Hoveyda听.

220.听鈥淒irect Synthesis of听Z-Alkenyl Halides through Catalytic Cross-Methathesis,鈥 M. J. Koh, T. T. Nguyen, H. Zhang, R. R. Schrock, A. H. Hoveyda听.

219.听鈥淩egarding a Persisting Puzzle in Olefin Metathesis with Ru Complexes: Why are Transformations of Alkenes with a Small Substituent听Z-Selective?,鈥 S. Torker, M. J. Koh, R. K. Khan, A. H. Hoveyda听.

218.听鈥淢echanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to 尾 Unsaturated Carbonyl Compounds鈥 H. Wu, J. M. Garcia, F. Haeffner, S. Radomkit, A. R. Zhugralin, A. H. Hoveyda听.

217.听鈥淣-Heterocyclic Carbene鈥揅opper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes,鈥 Y. Shi , B. Jung , S. Torker, A. H. Hoveyda听.

216.听鈥淣-Substituted Tertiary and O-Substituted Quaternary Carbon Stereogenic Centers by Site-, Diastereo- and Enantioselective Vinylogous Mannich Reactions,鈥 D. L. Silverio, P. Fu, E. L. Carswell, M. L. Snapper, A. H. Hoveyda听. (Special issue in memory of Professor Harry H. Wasserman)

215.听鈥淪ynthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand,鈥 J. C. Axtell, R. R. Schrock, Peter M眉ller, A. H. Hoveyda听.

214.听鈥淪ynthesis of Alternating听trans-AB Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Alkylidenes,鈥 H. Jeong, J. M. John, R. R. Schrock, A. H. Hoveyda.

213.听鈥淗igh-Value Alcohols and Higher-Oxidation-State Compounds by Catalytic听Z-Selective Cross-Metathesis,鈥 M. J. Koh, R. K. M. Khan, S. Torker, M. Yu, M. S. Mikus, A. H. Hoveyda听.

212.听鈥淐atalyst-Controlled Stereoselective Olefin Metathesis as a Principal Strategy in Multistep Synthesis Design: A Concise Route to (+)-Neopeltolide,鈥 M. Yu, R. R. Schrock, A. H. Hoveyda听.

211.听鈥淧reparation of Macrocyclic听Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis,鈥 H. Zhang, E. C. Yu, S. Torker, R. R. Schrock, A. H. Hoveyda听.

210.听鈥淐atalytic听Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1,鈥 A. W. H. Speed, T. J. Mann, R. V. O鈥橞rien, R. R. Schrock, A. H. Hoveyda听.

209.听鈥淩eactivity and Selectivity Differences between Catecholate and Catechothiolate Ru Complexes. Implications Regarding Design of Stereoselective Olefin Metathesis Catalysts,鈥 R. K. M. Khan, S. Torker, A. H. Hoveyda听.

208.听鈥淪ynthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands,鈥 E. M. Townsend, J. Hyvl, W. P. Forrest, R. R. Schrock, P. M眉ller, A. H. Hoveyda听.

207.听鈥淢ultifunctional Organoboron Compounds for Scalable Natural Product Synthesis,鈥 F. Meng, K. P. McGrath, A. H. Hoveyda听.

206.听鈥淪ynthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand,鈥 J. C. Axtell, R. R. Schrock, P. M眉ller, S. J. Smith, A. H. Hoveyda听.

205.听鈥淐atalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity,鈥 H. Jang, B. Jung, A. H. Hoveyda听.

204.听鈥淒iastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine鈥揅u Complex,鈥 F. Meng, F. Haeffner, A. H. Hoveyda听.

203.听鈥淪ynthesis of (卤)-Tetrapetalone A-Me Aglycon,鈥 P. N. Carlsen, T. J. Mann, A. H. Hoveyda, A. J. Frontier听.

202.听鈥淎n Efficient, Practical, and Enantioselective Method for Synthesis of Homoallenylamides Catalyzed by an Aminoalcohol-Derived, Boron-Based Catalyst,鈥 H. Wu, F. Haeffner, A. H. Hoveyda听.

201.听鈥淣HC鈥揅u-Catalyzed Addition of Propargylboron Reagents to Phosphinoylimines. Enantioselective Synthesis of Trimethylsilyl-Substituted Homoallenylamides and Application to the Synthesis of S-(鈥)-Cyclooroidin,鈥 N. W. Mszar, F. Haeffner, A. H. Hoveyda听.

200.听鈥淭he Influence of Anionic Ligands on Stereoisomerism of Ru Carbenes and Their Importance to Efficiency and Selectivity of Catalytic Olefin Metathesis Reactions,鈥 S. Torker, R. K. M. Khan, A. H. Hoveyda听.

199.听鈥淓nantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones,鈥 S. Radomkit, A. H. Hoveyda听.

198.听鈥淎 Broadly Applicable NHC鈥揅u-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis,鈥 F. Gao, J. L. Carr, A. H. Hoveyda听.

197.听鈥淏roadly Applicable听Z鈥 and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex,鈥 M. J. Koh, R. K. M. Khan, S. Torker, A. H. Hoveyda听.

196.听鈥淎 Multicomponent Ni-, Zr-, and Cu-Catalyzed Strategy for Enantioselective Synthesis of Alkenyl-Substituted Quaternary Carbons,鈥 K. P. McGrath, A. H. Hoveyda听.

195.听鈥淗igh Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes,鈥 E. M. Townsend, S. M. Kilyanek, R. R. Schrock, P.M眉ller, S. J. Smith, A. H. Hoveyda听.

194.听鈥淓nantioselective Silyl Protection of Alcohols Promoted by a Combination of Chiral and Achiral Lewis Basic Catalysts,鈥 N. Mannville, H. Alite, F. Haeffner, A. H. Hoveyda, M. L. Snapper听.

193.听鈥淐atalytic听Z-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis,鈥 T. J. Mann, A. W. H. Speed, R. R. Schrock, A. H. Hoveyda听.

192.听鈥淩eadily Accessible and Easily Modifiable Ru-Based Catalysts for Efficient and听Z-Selective Ring-Opening Metathesis Polymerization and Ring-Opening/Cross-Metathesis,鈥 R. K. M. Khan, S. Torker, A. H. Hoveyda听.

191.听鈥淓nantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Cu-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones,鈥 J. A. Dabrowski, M. T. Villaume, A. H. Hoveyda听.

190.听鈥淐ombining NHC鈥揅u and B脴nsted Base Catalysis: Enantioselective Allylic Substitition/Conjugate Addition with Alkynyllithium Reagents and Stereospecific Isomerization of Products to Trisubstituted Allenes,鈥 J. A. Dabrowski, J. Haeffner, A. H. Hoveyda听.

189.听鈥淪ynthesis of听Z-(Pinacolato)allylboron and听Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis,鈥 E. T. Kiesewetter, R. V. O鈥橞rien, E. C. Yu, S. J. Meek, R. R. Schrock, A. H. Hoveyda听.

188.听鈥淐u-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones,鈥 F. Meng, H. Jang, B. Jung, A. H. Hoveyda听.

187.听鈥淣HC-Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism,鈥 F. Meng, B. Jung, F. Haeffner, A. H. Hoveyda听.

186.听鈥淪imple Organic Molecules as Catalysts for Enantioselective Synthesis of Amines and Alcohols,鈥 D. Silverio, S. Torker, T. Pilyugina, E. M. Vieira, M. L. Snapper, F. Haeffner, A. H. Hoveyda听.

185.听鈥淓fficient and Selective Formation of Macrocyclic Disubstituted听Z听Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes: Applications to Total syntheses of Epilachnene, Yuzu Lactone, Ambrettolide, Epothilone C, and Nakadomarin A,鈥 C. Wang, M. Yu, A. F. Kyle, P. Jakubec, D. J. Dixon, R. R. Schrock, A. H. Hoveyda听.

184.听鈥淓xceptionally听E鈥 and 尾-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes,鈥 F. Meng, H. Jang, A. H. Hoveyda听.

183.听鈥淢olybdenum-Based Complexes with Two Aryloxides and a Pentafluoroimido Ligand: Catalysis for Efficient听Z-selective Synthesis of a Macrocylic Trisubstituted Alkene by Ring Closing Metathesis,鈥 C. Wang, F. Haeffner, R. R. Schrock, A. H. Hoveyda听.

182.听鈥淣HC鈥揅u-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes,鈥 K.-S. Lee, H. Wu, F. Haeffner, A. H. Hoveyda听.

181.听鈥Z鈥 and Enantioselective Ring-Opening/Cross-Metathesis with Enol Ethers Catalyzed by Stereogenic-at-Ru Carbenes: Reactivity, Selectivity, and Curtin-Hammett Kinetics,鈥 R. K. M. Khan, R. V. O鈥橞rien, S. Torker, B. Li, A. H. Hoveyda听.

180.听鈥淪ynthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways,鈥 R. K. M. Khan, A. R. Zhugralin, S. Torker, R. V. O鈥橞rien, P. J. Lombardi, A. H. Hoveyda听.

179.听鈥Z-selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes,鈥 E. M. Townsend, R. R. Schrock, A. H. Hoveyda听.

178.听鈥淏ipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes,鈥 A. G. Lichtscheidl, V. W. L. Ng, P. M眉ller, M. K. Takase, R. R. Schrock, S. J. Malcolmson, S. J. Meek, B. Li, E. T. Kiesewetter, A. H. Hoveyda听.

177.听鈥淐u-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents,鈥 F. Gao, J. L. Carr, A. H. Hoveyda听.

176.听鈥淎 Robust, Efficient and Highly Enantioselective Method for Synthesis of Homopropargyl Amines,鈥 E. M. Vieira, F. Haeffner, M. L. Snapper, A. H. Hoveyda听.

175.听鈥淢etal-Free Catalytic Enantioselective C-B Bond Formation: (Pinacolato)boron Conjugate Additions to 伪,尾-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes,鈥 H. Wu, S. Radomkit, J. M. O鈥橞rien, A. H. Hoveyda听.

174.听鈥淓nol Ethers as Substrates for Efficient听Z鈥 and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes. Utility in Chemical Synthesis and Mechanistic Attributes,鈥 M. Yu, I. Ibrahem, M. Hasegawa, R. R. Schrock, A. H. Hoveyda听.

173.听鈥淪ite- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Allylic Substitution,鈥 B. Jung, A. H. Hoveyda听.

172.听鈥Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes,鈥 D. V. Peryshkov, R. R. Schrock, M. K. Takase, P. M眉ller, A. H. Hoveyda听.

171.听鈥淪ynthesis of Macrocyclic Natural Products by Catalyst-Controlled Stereoselective Ring-Closing Metathesis,鈥 M. Yu, C. Wang, A. F. Kyle, P. Jakubec, D. J. Dixon, R. R. Schrock, A. H. Hoveyda听.

170.听鈥淚solation of Pure Disubstituted听E听Olefins through Mo-Catalyzed听Z-Selective Ethenolysis of Stereoisomeric Mixtures,鈥 S. C. Marinescu, D. S. Levine, Y. Zhao, R. R. Schrock, A. H. Hoveyda听.

169.听鈥淩egiodivergent Reactions through Catalytic Enantioselective Silylation of Chiral Diols. Synthesis of Sapinofuranone A,鈥 J. M. Rodrigo, Y. Zhao, A. H. Hoveyda, M. L. Snapper听.

168.听鈥淣HC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes,鈥 R. Corberan, N. W. Mszar, A. H. Hoveyda听.

167.听鈥淢etal-Free Catalytic C-Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic 伪,尾-Unsaturated Carbonyls,鈥 J. M. O鈥橞rien, A. H. Hoveyda听.

166.听鈥淗ighly Selective Methods for Synthesis of Internal (伪-) Vinylboronates through Efficient NHC-Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity,鈥 H. Jang, A. R. Zhugralin, Y. Lee, A. H. Hoveyda听.

165.听鈥淩oom-Temperature听Z-Selective Homocoupling of 伪-Olefins by Tungsten Catalysts,鈥 S. C. Marinescu, R. R. Schrock, P. M眉ller, M. K. Takase, A. H. Hoveyda听.

164.听鈥淓nantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents,鈥 J. A. Dabrowski, F. Gao, A. H. Hoveyda听.

163.听鈥淐atalytic听Z-Selective Olefin Cross-Metathesis for Natural Product Synthesis,鈥 S. J. Meek, R. V. O鈥橞rien, J. Llaveria, R. R. Schrock, A. H. Hoveyda听.

162.听鈥淓nantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl- or Alkene-Substituted Aldimines Catalyzed by Chiral听C-Symmetric NHC-Cu-Complexes,鈥 E. M. Vieira, M. L. Snapper, A. H. Hoveyda听.

161.听鈥Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-W Mono-Pyrrolide Complexes,鈥 Y. Zhao, A. H. Hoveyda, R. R. Schrock听.

160.听鈥淔ormation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC-Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to 尾-Substituted Cyclic Enones,鈥 T. L. May, J. A. Dabrowski, A. H. Hoveyda听.

159.听鈥淪ynthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinyaluminum Reagents,鈥 F. Gao, K. P. McGrath, Y. Lee, A. H. Hoveyda听.

158.听鈥淨uaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Hetero-aryllithium Reagents and Aluminum Chlorides,鈥 F. Gao, Y. Lee, K. Mandai, A. H. Hoveyda听.

157.听鈥溛 -Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes. Practical Syntheses of Internal Vinyl Aluminums, Halides or Boronates,鈥 F. Gao, A. H. Hoveyda听.

155.听鈥淓nantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions,鈥 A. Guzman-Martinez, A. H. Hoveyda听.

154.听鈥淓nantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes,鈥 K.-S. Lee, A. H. Hoveyda听.

153.听鈥淪tereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Cu-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing听Z听or听E听alkenes,鈥 K. Akiyama, F. Gao, A. H. Hoveyda听.

152.听鈥淰icinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC-Cu-Catalyzed Boron-Copper Additions to Terminal Alkynes,鈥 Y. Lee, H. Jang, A. H. Hoveyda听.

151.听鈥淗ighly听Z-Selective Metathesis Homocoupling of Terminal Olefins,鈥 A. J. Jiang, Y. Zhao, R. R. Schrock, A. H. Hoveyda听.

150.听鈥淭he Significance of Degenerate Processes to Enantioselective Olefin Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes,鈥 S. J. Meek, S. J. Malcolmson, B. Li, R. R. Schrock, A. H. Hoveyda听.

149.听鈥淓thenolysis Reactions Catalyzed by Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum,鈥 S. C. Marinescu, R. R. Schrock, P. M眉ller, A. H. Hoveyda听.

148.听鈥淪tereogenic-at-Metal Zn- and Al-based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations,鈥 Y. Lee, B. Li, A. H. Hoveyda听.

147.听鈥Endo-Selective Enyne Ring-Closing Metathesis Promoted by Stereogenic-at-Mo Monoalkoxide and Monoaryloxide Complexes. Efficient Synthesis of Cyclic Dienes Not Accessible through Reactions with Ru Carbenes,鈥 Y.-J. Lee, R. R. Schrock, A. H. Hoveyda听.

146.听鈥淗-Bonding as an Control Element in Stereoselective Ru-Catalyzed Olefin Metathesis,鈥 A. H. Hoveyda, P. J. Lombardi, R. V. O鈥橞rien, A. R. Zhugralin听.

145.听鈥Z-Selective Olefin Metathesis Processes Catalyzed by a Molybdenum Hexaisopropylterphenoxide Monopyrrolide Complex,鈥 M. M. Flook, A. J. Jiang, R. R. Schrock, P. M眉ller, A. H. Hoveyda听.

144.听鈥淢onodentate Non-C2-Symmetric Chiral听N-Heterocyclic Carbene Complexes for Enantioselective听Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones,鈥 K.-S. Lee, A. H. Hoveyda听.

143.听鈥淓fficient C-B Bond Formation Promoted by听N-Heterocyclic Carbenes. Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic 伪,尾-Unsaturated Carbonyls,鈥 K.-S. Lee, A. R. Zhugralin, A. H. Hoveyda听.

142.听鈥淓fficient Boron-Copper Additions to Aryl-Substituted Alkenes Promoted by NHC-Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions,鈥 Y. Lee, A. H. Hoveyda听.

141.听鈥淗ighly听Z鈥 and Enantioselective Ring-Opening/Cross Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes,鈥 I. Ibrahem, M. Yu, R. R. Schrock, A. H. Hoveyda听.

140.听鈥淒esign and Stereoselective Preparation of a New Class of Chiral Olefin Metathesis Catalysts and Application to Enantioselective Synthesis of Quebrachamine. Catalyst Development Inspired by Natural Product Synthesis,鈥 E. S. Sattely, S. J. Meek, S. J. Malcolmson, R. R. Schrock, A. H. Hoveyda听.

139.听鈥淚nversion of Configuration at the Metal in Diastereomeric Imido Alkylidene Monoaryloxide Monopyrrolide (MAP) Complexes of Molybdenum,鈥 S. C. Marinescu, R. R. Schrock, B. Li, A. H. Hoveyda听.

138.听鈥淓nantioselective Synthesis of P-Stereogenic Phosphinates and Phosphine Oxides by Mo-Catalyzed Asymmetric Ring-Closing Metathesis,鈥 J. S. Harvey, S. J. Malcolmson, K. S. Dunne, S. J. Meek, A. L. Thompson, R. R. Schrock, A. H. Hoveyda, V. Gouverneur听.

137.听鈥淐atalytic Enantioselective Silylation of Acyclic and Cyclic Triols and Application to Total Syntheses of Cleroindicins D, F, and C,鈥 Z. You, A. H. Hoveyda, M. L. Snapper听.

136.听鈥淎g-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of 伪-Ketoimine Esters. Development of a Method and Investigation of its Mechanism,鈥 L. C. Wieland, E. M. Vieira, M. L. Snapper, A. H. Hoveyda听.

135.听鈥淭hree-Component Ag-Catalyzed Enantioselective Vinylogous Mannich and Aza-Diels-Alder Reactions with Alkyl-Substituted Aldehydes,鈥 H. Mandai, K. Mandai, M. L. Snapper, A. H. Hoveyda听.

134.听鈥淗ighly Efficient Molybdenum-Based Catalysts for Enantioselective Alkene Metathesis,鈥 S. J. Malcolmson, S. J. Meek, E. S. Sattely, R. R, Schrock, A. H. Hoveyda听.

133.听鈥淓nantioselective Total Synthesis of Clavirolide C. Applications of Cu-Catalyzed Asymmetric Conjugate Additions and Ru-Catalyzed Ring-Closing Methathesis,鈥 M. K. Brown, A. H. Hoveyda听.

132.听鈥淓nantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring 尾-Substituted Cyclic Enones,鈥 T. L. May, M. K. Brown, A. H. Hoveyda听.

131.听鈥淎luminum-Catalyzed Asymmetric Alkylations of Pyridyl-Substituted Alkynyl Ketones with Dialkylzinc Reagents,鈥 D. K. Friel, M. L. Snapper, A. H. Hoveyda听.

130.听鈥淐atalytic Asymmetric Alkylations of Ketoimines. Enantioselective Synthesis of N-Substituted Quaternary Carbon Stereogenic Centers by Zr-Catalyzed Additions of Dialkylzinc Reagents to Aryl-, Alkyl- and Trifluoroalkyl-Substituted Ketoimines,鈥 P. Fu, M. L. Snapper, A. H. Hoveyda听.

129.听鈥淗ighly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents,鈥 Y. Lee, K. Akiyama, D. Gillingham, M. K. Brown, A. H. Hoveyda听.

128.听鈥淜inetic Resolution of 1,2-Diols through Highly Site- and Enantioselective Catalytic Silylation,鈥 Y. Zhao, A. W. Mitra, A. H. Hoveyda, M. L. Snapper听.

127.听鈥淪ynthesis of Monoalkoxide Monopyrrolyl Complexes of the Type Mo(NR)(CHR鈥)(OR鈥)(pyrrolyl). Enyne Metathesis with High Oxidation State Catalysts,鈥 R. Singh, R. R. Schrock, P. M眉ller, A. H. Hoveyda听.

126.听鈥淐u-Catalyzed Asymmetric Conjugate Additions of Dialkyl- and Diarylzinc Reagents to Acyclic 尾-Silyl-伪 , 尾-Unsaturated Ketones. Synthesis of Allylsilanes in High Diastereo- and Enantiomeric Purity,鈥 M. A. Kacprzynski, S. A. Kazane, T. L. May, A. H. Hoveyda听.

125.听鈥淐omparison of Ru- and Mo- Based Chiral Olefin Metathesis Catalysts. Complementarity in Asymmetric Ring-Opening/Cross-Metathesis Reactions of Oxa- and Azabicycles,鈥 G. A. Cortez, C. A. Baxter, R. R. Schrock, A. H. Hoveyda听.

124.听鈥淢olybdenum Imido Alkylidene Metathesis Catalysts That Contain Electron-Withdrawing Biphenolates or Binaphtholates,鈥 R. Singh, C. Czekelius, R. R. Schrock, P. M. M眉ller, A. H. Hoveyda听.

122.听鈥淓fficient Enantioselective Synthesis of Piperidines through Catalytic Asymmetric Ring-Opening/Cross Metathesis Reactions,鈥 G. A. Cortez, R. R. Schrock, A. H. Hoveyda听.

121.听鈥淒irected Catalytic Asymmetric Olefin Metathesis. Selectivity Control by Enoate and Ynoate Groups in Ru-Catalyzed Asymmetric Ring-Opening/Cross Metathesis,鈥 R. E. Guidici, A. H. Hoveyda听.

120.听鈥淐hiral N-Heterocyclic Carbenes in Natural Product Synthesis. Application of Ru-Catalyzed Asymmetric Ring-Opening/Cross Metathesis and Cu-Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C,鈥 D. G. Gillingham, A. H. Hoveyda听.

119.听鈥淣ew Enantiomerically Pure Alkyimido Molybdenum-Based Alkylidene Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts,鈥 T. S. Pilyugina, R. R. Schrock, P. M眉ller, A. H. Hoveyda听.

118.听鈥淎ll-Carbon Quaternary Stereogenic Centers by Enantioselective Cu-Catalyzed Conjugate Additions Promoted by a Chiral N-Heterocyclic Carbene,鈥 M. K. Brown, T. L. May, C. A. Baxter, A. H. Hoveyda听.

117.听鈥淒ipyrrolyl Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts,鈥 A. S. Hock, R. R. Schrock, A. H. Hoveyda听.

116.听鈥淟ewis Base Activation of Grignard Reagents with N-Heterocyclic Carbenes. Cu-Free Catalytic Enantioselective Additions to 纬-Chloro 伪 -,尾-Unsaturated Esters,鈥 Y. Lee, A. H. Hoveyda听.

115.听鈥淎 Highly Efficient and Practical Method for Catalytic Asymmetric Vinylogous Mannich (AVM) Reactions,鈥 E. L. Carswell, M. L. Snapper, A. H. Hoveyda听.

114.听鈥淒iphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts,鈥 A. Sinha, R. R. Schrock, P. Muller, A. H. Hoveyda听.

113.听鈥淓nantioselective Silyl Protection of Alcohols Catalysed by an Amino Acid-Based Small-Molecule,鈥 Y. Zhao, J. Rodrigo, A. H. Hoveyda, M. L. Snapper听.

112.听鈥淎 Practical Method for Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers through NHC-Cu-Catalyzed Conjugate Additions of Alkyl- and Arylzinc Reagents to 尾-Substituted Cyclic Enones,鈥 K.-S. Lee, M. K. Brown, A. W. Hird, A. H. Hoveyda听.

111.听鈥淎 Chiral Ag-based Catalyst for Practical, Efficient and Highly Enantioselective Additions of Enolsilanes to 伪-Ketoesters,鈥 L. C. Akullian, M. L. Snapper, A. H. Hoveyda听.

110.听鈥淥perationally Simple, Efficient, and Diastereoselective Synthesis of听cis-2,6-Disubstituted-4-Methylene Tetrahydropyrans Catalyzed by Triflic Acid,鈥 A. Puglisi, A.-L. Lee, R. R. Schrock, A. H. Hoveyda听.

109.听鈥淓nantioselective Synthesis of Cyclic Enol Ethers and All-Carbon Quaternary Stereogenic Centers through Catalytic Asymmetric Ring-Closing Metathesis,鈥 A.-L. Lee, S. J. Malcolmson, A. Puglisi, R. R. Schrock, A. H. Hoveyda听.

108.听鈥淎l-Catalyzed Enantioselective Alkylation of 伪-Ketoesters by Dialkylzinc Reagents. Enhancement of Enantioselectivity and Reactivity by an Achiral Lewis Base Additive,鈥 L. C. Wieland, H. Deng, M. L. Snapper, A. H. Hoveyda听.

107.听鈥淐atalytic Enantioselective Alkylations of Tetrasubstituted Olefins. Synthesis of All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Enones,鈥 A. W. Hird, A. H. Hoveyda听.

106.听鈥淗ighly Enantioselective Cu-Catalyzed Conjugate Additions of Dialkylzinc Reagents to Unsaturated Furanones and Pyranones: Preparation of Air Stable and Catalytically Active Cu.Peptide Complexes,鈥 M. K. Brown, S. J. Degrado, A. H. Hoveyda听.

105.听鈥淧roline-Based听N-Oxides as Readily Available and Modular Chiral Catalysts. Enantioselective Reactions of Allyltrichlorosilane with Aldehydes,鈥 J. F. Traverse, Y. Zhao, A. H. Hoveyda, M. L. Snapper听.

104.听鈥淧ractical and Highly Enantioselective Synthesis of 尾-Alkynyl-尾-amino Esters through Ag-Catalyzed Asymmetric Mannich Reactions of Silylketene Acetals and Alkynyl Imines,鈥 N. S. Josephsohn, E. L. Carswell, M. L. Snapper, A. H. Hoveyda听.

103.听鈥淓nantioselective Synthesis of Cyclic Amides and Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis,鈥 E. S. Sattely, G. A. Cortez, D. C. Moebius, R. R. Schrock, A. H. Hoveyda听.

102.听鈥淚socomplestatin: Total Synthesis and Stereochemical Revision,鈥 T. Shinohara, H. Deng, M. L. Snapper, A. H. Hoveyda听.

101.听鈥淎 Readily Available Chiral Ag-Based N-Heterocyclic Carbene Complex for Use in Efficient and Highly Enantioselective Ru-Catalyzed Olefin Metathesis and Cu-Catalyzed Allylic Alkylation Reactions,鈥 J. J. Van Veldhuizen, J. E. Campbell, R. E. Guidici, A. H. Hoveyda听.

100.听鈥淓nantioselective Synthesis of Nitroalkanes Bearing All-Carbon Quaternary Stereogenic Centers through Cu-Catalyzed Asymmetric Conjugate Additions,鈥 J. Wu, D. M. Mampreian, A. H. Hoveyda听.

99.听鈥淐atalytic Enantioselective Synthesis of Quaternary All-Carbon Stereogenic Centers. Preparation of 伪,伪鈥-Disubstituted-尾,纬-Unsaturated Esters through Cu-Catalyzed Asymmetric Allylic Alkylations,鈥 K. E. Murphy, A. H. Hoveyda听.

98.听鈥淎symmetric Synthesis of Acyclic Amines Through Zr- and Hf-Catalyzed Enantioselective Addition of Alkylzinc Reagents to Imines,鈥 L. C. Akullian, J. R. Porter, J. F. Traverse, M. L. Snapper, A. H. Hoveyda听.

97.听鈥淩egarding the Mechanism of Olefin Metathesis with Sol-Gel-Supported Ru-Based Complexes Bearing a Bidentate Carbene Ligand. Spectroscopic Evidence for Return of the Propagating Ru Carbene,鈥 J. S. Kingsbury, A. H. Hoveyda听.

96.听鈥淓fficient Enantioselective Synthesis of Functionalized Tetrahydropyrans by Ru-Catalyzed Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM),鈥 D. G. Gillingham, O. Kataoka, S. B. Garber, A. H. Hoveyda听.

95.听鈥淏identate NHC-Based Chiral Ligands for Efficient Cu-Catalyzed Enantioselective Allylic Alkylations: Structure and Activity of an Air-Stable Chiral Cu Complex,鈥 A. O. Larsen, W. Leu, C. N. Oberhuber, J. E. Campbell, A. H. Hoveyda听.

94.听鈥淓fficient Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Aromatic and Aliphatic Acyclic Nitroalkenes,鈥 D. M. Mampreian, A. H. Hoveyda听.

93.听鈥淚nvestigations of Reactions between Chiral Molybdenum Imido Alkylidene Complexes and Ethylene: Observation of Unsolvated Base-Free Methylene Complexes, Metalacyclobutane and Metalacyclopentane Complexes, and Molybdenum(IV) Olefin Complexes,鈥 W. C. P. Tsang, J. Y. Jamieson, S. L. Aeilts, K. C. Hultzsch, R. R. Schrock, A. H. Hoveyda听.

92.听鈥淪upported Chiral Mo-Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis,鈥 S. J. Dolman, K. C. Hultzsch, F. Pezet, X. Teng, A. H. Hoveyda, R. R. Schrock听.

91.听鈥淓nantioselective Synthesis of Cyclic Allylboronates by Mo-catalyzed Asymmetric Ring-Closing Metathesis (ARCM). A One-Pot Protocol for Net Catalytic Enantioselective Cross Metathesis,鈥 J. A. Jernelius, R. R. Schrock, A. H. Hoveyda听.

90.听鈥淐u-Catalyzed Asymmetric Allylic Alkylations of Aromatic and Aliphatic Phosphates with Alkylzinc Reagents. An Effective Method for Enantioselective Synthesis of Tertiary and Quaternary Carbons, 鈥 M. A. Kacprzynski, A. H. Hoveyda听.

89.听鈥淎g-Catalyzed Asymmetric Mannich Reactions of Enol Ethers with Aryl, Alkyl, Alkenyl, and Alkynyl Imines,鈥 N. S. Josephsohn, M. L. Snapper, A. H. Hoveyda听.

88.听鈥淐atalytic Homologation of Vinyltributylstannane to Allyltributylstannae by Mo(IV) Complexes in the Presence of Ethylene,鈥 R. R. Schrock, M. Duval-Lungulescu, W. C. P. Tsang, A. H. Hoveyda听.

87.听鈥淢o-Catalyzed Asymmetric Olefin Metathesis in Target-Oriented Synthesis. Enantioselective Synthesis of (+)-Africanol,鈥 G. S. Weatherhead, G. A. Cortez, R. R. Schrock, A. H. Hoveyda听.

86.听鈥淓nantioselective Total Synthesis of Erogorgiaene: Applications of Asymmetric Cu-Catalyzed Conjugate Additions of Alkylzincs to Acyclic Enones,鈥 R. R. Cesati, J. de Armas, A. H. Hoveyda听.

85.听鈥淓nantioselective Synthesis of Cyclic Secondary Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis (ARCM),鈥 S. J. Dolman, R. R. Schrock, A. H. Hoveyda听.

84.听鈥淐hiral Ru-Based Complexes for Asymmetric Olefin Metathesis: Enhancement of Catalytic Activity through Steric and Electronic Modifications鈥, J. J. Van Veldhuizen, D. G. Gillingham, S. B. Garber, O. Kataoka, A. H. Hoveyda听.

83.听鈥淭hree-Component Enantioselective Synthesis of Propargylamines through Zr-Catalyzed Additions of Alkyl Zinc Reagents to Alkynylimines,鈥 L. C. Akullian, M. L. Snapper, A. H. Hoveyda听.

82.听鈥淓nantioselective Synthesis of Propargylamines through Zr-Catalyzed Addition of Mixed Alkynylzinc Reagents to Arylimines,鈥 J. F. Traverse, A. H. Hoveyda, M. L. Snapper听.

81.听鈥淭otal Synthesis of Anti-HIV Chloropeptin I,鈥 H. Deng, J-K. Jung, T. Liu, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda听.

80.听鈥淓nantioselective Synthesis of 伪-Alkyl-尾,纬-unsaturated Esters through Efficient Cu-Catalyzed Allylic Alkylations,鈥 K. E. Murphy, A. H. Hoveyda听.

79.听鈥淓fficient and Practical Ag-Catalyzed Cycloadditions between Arylimines and the Danishefsky Diene,鈥 N. S. Josephsohn, M. L. Snapper, A. H. Hoveyda听.

78.听鈥淐u-Catalyzed Enantioselective Conjugate Additions of Alkyl Zinc Reagents to Unsaturated听N-Acyloxazolidinones Promoted by a Chiral Triamide Phosphane,鈥 A. W. Hird, A. H. Hoveyda听.

77.听鈥淎n Enantiomerically Pure Adamantylimido Molybdenym Alkylidene Complex. An Effective New Catalyst for Enantioselective Olefin Metathesis,鈥 W. C. P. Tsang, J. A. Jernelius, G. A. Cortez, G. S. Weatherhead, R. R. Schrock, A. H. Hoveyda听.

76.听鈥淎lkylidene and Metalacyclic Complexes of Tungsten that Contain a Chiral Biphenoxide Ligand. Synthesis, Asymmetric Ring-Closing Metathesis, and Mechanistic Investigations,鈥 W. C. P. Tsang, K. C. Hultzsch, J. B. Alexander, P. J. Bonitatebus, Jr., R. R. Schrock, A. H. Hoveyda听

75.听鈥淶r-Catalyzed Diastereo- and Enantioselective Diene Cyclizations. An Unexpected Synthesis of Chiral Aldehydes,鈥 S. J. Degrado, J. A. Adams, A. H. Hoveyda听.

74.听鈥淓fficient Cu-Catalyzed Asymmetric Conjugate Additions of Allylzincs to Trisubstituted Cyclic Enones,鈥 S. J. Degrado, H. Mizutani, A. H. Hoveyda听.

73.听鈥淓nhancement of Enantioselectivity by THF in Asymmetric Mo-Catalyzed Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Tertiary Ethers and Spirocycles,鈥 X. Teng, D. R. Cefalo, R. R. Schrock, A. H. Hoveyda听.

72.听鈥淐u鈥揅atalyzed Enantioselective Conjugate Addition of Alkylzincs to Cyclic Nitroalkenes: Catalytic Asymmetric Synthesis of Cyclic 伪-Substituted Ketones,鈥 C. A. Luchaco-Cullis, A. H. Hoveyda听.

71.听鈥淓fficient Catalytic Enantioselective Synthesis of Unsaturated Amines: Preparation of Small- and Medium-Ring Cyclic Amines through Mo-Catalyzed Asymmetric Ring-Closing Metathesis in the Absence of Solvent,鈥 S. J. Dolman, E. S. Sattely, A. H. Hoveyda, R. R. Schrock.

70.听鈥淎 Recyclable Chiral Ru Catalyst for Enantioselective Olefin Metathesis. Efficient Catalytic Asymmetric Ring-Opening/Cross Metathesis in Air,鈥 J. J. Van Veldhuizen, S. B. Garber, J. S. Kingsbury, A. H. Hoveyda听.

69.听鈥淓nantioselective Synthesis of Medium Ring Heterocycles, Tertiary Ethers and Tertiary Alcohols by Mo-Catalyzed Ring-Closing Metathesis,鈥 A. F. Kiely, J. A. Jernelius, R. R. Schrock, A. H. Hoveyda听.

68.听鈥淥lefins Turned Alkylating Agents: Diastereoselective Intramolecular Zr-Catalyzed Olefin Alkylations,鈥 R. R. Cesati III, J. de Armas, A. H. Hoveyda听.

67.听鈥淎luminum-Catalyzed Asymmetric Addition of TMSCN to Aromatic and Aliphatic Ketones Promoted by an Easily Accessible and Recyclable Peptide Ligand,鈥 H. Deng, M. P. Isler, M. L. Snapper, A. H. Hoveyda听<a href="https://doi.org/10.1002/1521-3773(20020315)41:63.0.CO;2-F鈥>Angew. Chem., Int. Ed.2002,听41, 1009.

66.听鈥淭he First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis,鈥 K. C. Hultszch, J. A. Jernelius, A. H. Hoveyda, R. R. Schrock听<a href="https://doi.org/10.1002/1521-3773(20020215)41:43.0.CO;2-V鈥>Angew. Chem., Int. Ed.2002,听41, 589.

65.听鈥淐u-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Acyclic Aliphatic Enones,鈥 H. Mizutani, S. J. Degrado, A. H. Hoveyda听.

64.听鈥淣ew Chiral Molybdenum Catalysts for Asymmetric Olefin Metathesis that Contain 3,3鈥-Disubstituted Octahydrobinaphtholate or 2,6-Dichlorophenylimido Ligands,鈥 R. R. Schrock, J. Y. Jamieson, S. J. Dolman, S. A. Miller, P. J. Bonitatebus, A. H. Hoveyda听.

63.听鈥淓valuation of Enantiomerically Pure Binaphthol-Based Molybdenum Catalysts for Asymmetric Olefin Metathesis Reactions that Contain 3,3鈥-Diphenyl- or 3,3鈥-Dimesityl-Substituted Binaphtholate Ligands. Generation and Decomposition of Unsubstituted Molybdacyclobutane Complexes,鈥 W. C. P. Tsang, R. R. Schrock, A. H. Hoveyda听.

62.听鈥淚mmobilization of Olefin Metathesis Catalysts on Monolithic Sol-Gel. Practical, Efficient and Easily Recyclable Catalysts for Organic and Combinatorial Synthesis,鈥 J. S. Kingsbury, S. B. Garber, J. M. Giftos, B. L. Gray, M. M. Okamoto, R. A. Farrer, J. T. Fourkas, A. H. Hoveyda听<a href="https://doi.org/10.1002/1521-3773(20011119)40:223.0.CO;2-L鈥>Angew. Chem., Int. Ed.听2001,听40, 4251.

61.听鈥淢echanism of Enantioselective Ti-Catalyzed Strecker Reaction: Peptide-Based Metal Complexes as Bifunctional Catalysts,鈥 N. S. Josephson, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda听.

60.听鈥淭hree-Component Catalytic Asymmetric Synthesis of Aliphatic Amines,鈥 J. R. Porter, J. F. Traverse, A. H. Hoveyda, M. L. Snapper听.

59.听鈥淢olybdenum Imido Alkylidene Complexes Containing Biphen Ligands That Have Silyl Groups Attached through the 6 and 6鈥 Methyl Group Carbon Atoms,鈥 K. C. Hultszch, P. J. Bonitatebus, J. Jernelius, R. R. Schrock, A. H. Hoveyda.

58.听鈥淶r-Catalyzed Electrophilic Carbomagnesation of Aryl Olefins. Mechanism-Based Control of Zr-Mg Ligand Exchange,鈥 J. de Armas, A. H. Hoveyda听.

57.听鈥淐atalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis (AROM/CM) Reactions. Mechanism and Application to Enantioselective Synthesis of Functionalized Cyclopentanes,鈥 D. S. La, E. S. Sattely, J. G. Ford, R. R. Schrock, A. H. Hoveyda.

56.听鈥淢odular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Cu-Catalyzed Allylic Substitutions,鈥 C. A. Luchaco-Cullis, H. Mizutani, K. E. Murphy, A. H. Hoveyda听<a href="https://doi.org/10.1002/1521-3773(20010417)40:83.0.CO;2-T鈥>Angew. Chem., Int. Ed.2001,听40, 1456.

55.听鈥淎 Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis,鈥 S. L. Aeilts, D. R. Cefalo, P. J. Bonitatebus, Jr., J. H. Houser, A. H. Hoveyda, R. R. Schrock听<a href="https://doi.org/10.1002/1521-3773(20010417)40:83.0.CO;2-G鈥>Angew. Chem., Int. Ed.2001,听40, 1452.

54.听鈥淓nantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers by Mo-Catalyzed Olefin Metathesis,鈥 D. R. Cefalo, A. F. Kiely, M. Wuchrer. J. Y. Jamieson, R. R. Schrock, A. H. Hoveyda听.

53.听鈥淐ross-Metathesis Reaction. Generation of Highly Functionalized Olefins from Unsaturated Alcohols,鈥 J. Cossy, S. BouzBouz, A. H. Hoveyda听.

52.听鈥淓nantioselective Synthesis of Arylamines Through Zr-Catalyzed Addition of Dialkylzincs to Imines. Reaction Development by Screening of Parallel Libraries,鈥 J. R. Porter, J. F. Traverse, A. H. Hoveyda, M. L. Snapper听.

51.听鈥淢odular Peptide-Based Phosphine Ligands in Asymmetric Catalysis: Efficient and Enantioselective Cu-Catalyzed Conjugate Additions to Five-, and Six- and Seven-Membered Cyclic Enones,鈥 S. J. Degrado, H. Mizutani, A. H. Hoveyda听.

50.听鈥淪ynthesis of Molybdenum Imido Alkylidene Complexes that Contain 3,3鈥-Dialkyl-5,5鈥,6,6鈥-tetramethyl-1,1鈥-biphenyl-2,2鈥-diolates (Alkyl =听t-Bu or Adamantyl). Catalysts for Enantioselective Olefin Metathesis Reactions,鈥 J. B. Alexander, R. R. Schrock, W. M. Davis, W., K. C. Hultzsh, A. H. Hoveyda, J. H. Houser,听.

49.听鈥淢odular Mo-Based Catalysts for Efficient Asymmetric Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Ethers and Acetals,鈥 G. S. Weatherhead, J. H. Houser, J. G. Ford, J. Y. Jamieson, R. R. Schrock, A. H. Hoveyda听.听 (Special issue in celebration of the 80th听birthday of Professor Harry H. Wasserman)

48.听鈥淓fficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts,鈥 S. B. Garber, J. S. Kingsbury, B. L. Gray, A. H. Hoveyda听.

47.听鈥淶r-Catalyzed Olefin Alkylations and Allylic Substitution Reactions with Electrophiles,鈥 J. de Armas, S. P. Kolis, A. Hoveyda听.

46.鈥淭i-Catalyzed Regio- and Enantioselective Synthesis of Unsaturated 伪-Amino Nitriles, Amides and Acids. Catalyst Identification through Screening of Parallel Libraries,鈥 J. R. Porter, W. G. Wirschun, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda听.

45.听鈥淪ynthesis of Molybdenum Imido Alkylidene Complexes Containing N,N鈥-Disubstituted 2,2鈥-Bisamido-1,1鈥-binaphthyl Ligands,鈥 J. Y. Jamieson, R. R. Schrock, W. M. Davis, P. J. Bonitatebus, S. S. Zhu, A. H. Hoveyda听.

44.听鈥淭andem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis,鈥 G. S. Weatherhead, G. J. Ford, E. J. Alexanian, R. R. Schrock, A. H. Hoveyda听.

43.听鈥淶r-Catalyzed Kinetic Resolution of Aliphatic Cyclic Allylic Ethers. Carbocycles to Heterocycles by Ru- and Mo-Catalyzed Ring-Opening and Ring-Closing Metathesis,鈥 J. A. Adams, J. G. Ford, P. J. Stamatos, A. H. Hoveyda听.

42.听鈥淭andem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis,鈥 D. S. La, J. G. Ford, E. S. Sattely, P. J. Bonitatebus, R. R. Schrock, A. H. Hoveyda听.

41.听鈥淐hiral Mo-Binol Complexes: Activity, Synthesis, and Structure. Efficient Enantioselective Six-Membered Ring Synthesis through Catalytic Metathesis,鈥 S. S. Zhu, D. R. Cefalo, D. S. La, J. Y. Jamieson, W. M. Davis, A. H. Hoveyda, R. R. Schrock听.

40.听鈥淭i-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure 伪-Amino Acids, 鈥 C. A. Krueger, K. W. Kuntz, C. D. Dzierba, W. G. Wirschun, J. D. Gleason, M. L. Snapper, A. H. Hoveyda听.

39.听鈥淪tereoselective Chelate-Controlled Addition of Grignard Reagents to Unsaturated Medium-Ring Heterocycles,鈥 J. A. Adams, N. M. Heron, A. M. Koss, A. H. Hoveyda听.

38.听鈥淒iastereoselective Intramolecular Cycloaddition of Vinylsilanes and Silyl Nitronates. Effective Control of Remote Acyclic Asymmetry,鈥 D. G. J. Young, E. Gomez-Bengoa, A. H. Hoveyda听.

37.听鈥淎 Recyclable Ru-Based Metathesis Catalyst,鈥 J. S. Kingsbury, J. P. A. Harrity, P. J. Bonitatebus, A. H. Hoveyda听.

36.听鈥淢o-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing Metathesis,鈥 D. S. La, J. B. Alexander, D. R. Cefalo, D. D. Graf, A. H. Hoveyda, R. R. Schrock听.

35.听鈥淶r-Catalyzed Kinetic Resolution of Allylic Ethers and Mo-Catalyzed Chromene Formation in Synthesis. Enantioselective Total Synthesis of the Antihypertensive Agent (S,R,R,R)-Nebivolol,鈥 C. W. Johannes, M. S. Visser, G. S. Weatherhead, A. H. Hoveyda听.

34.听鈥淐atalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen-Mo Complex,鈥 J. B. Alexander, D. S. La, D. R. Cefalo, A. H. Hoveyda, R. R. Schrock听.

33.听鈥淣i-Catalyzed Asymmetric Addition of Grignard Reagents to Unsaturated Cyclic Acetals. The Influence of Added Phosphine on Enantioselectivity,鈥 E. Gomez-Bengoa, N. M. Heron, M. T. Didiuk, C. A. Luchaco, A. H. Hoveyda听.

32.听鈥淐hromenes through Metal-Catalyzed Reactions of Styrenyl Ethers. Mechanism and Utility in Synthesis,鈥 J. P. A. Harrity, D. S. La, D. R. Cefalo, M. S. Visser, A. H. Hoveyda听.

31.听鈥淧hosphine-Directed Stereo- & Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers,鈥 M. T. Didiuk, J. P. Morken, A. H. Hoveyda听.

30.听鈥淎pplications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B1),鈥 Z. Xu, C. W. Johannes, A. F. Houri, D. S. La, D. A. Cogan, G. E. Hofilena, A. H. Hoveyda听.

29.听鈥淪tereoselective Heteroatom-Assisted Allylic Alkylation of Cyclic Ethers With Grignard Reagents. A Convenient Route to Enantiomerically Pure Carbocycles,鈥 N. M. Heron, J. A. Adams, A. H. Hoveyda听.

28.听鈥淪earch for Chiral Catalysts Through Ligand Diversity: Substrate-Specific Catalysts and Ligand Screening on Solid Support,鈥 K. D. Shimizu, B. M. Cole, C. A. Krueger, K. W. Kuntz, M. L. Snapper, A. H. Hoveyda听.

27.听鈥淪ynthesis of Amino Sugars Through a Highly Diastereoselective Dipolar Cycloaddition. Enantioselective Synthesis of the Carbohydrate Segment of Sch 38516,鈥 Z. Xu, C. W. Johannes, D. S. La, G. E. Hofilena, A. H. Hoveyda听.

26.听鈥淩u-Catalyzed Rearrangement of Styrenyl Ethers. Enantioselective Synthesis of Chromenes Through Zr- and Ru-Catalyzed Processes,鈥 J. P. A. Harrity, M. S. Visser, J. D. Gleason, A. H. Hoveyda听.

25.听鈥淓nantioselective Total Synthesis of Antifungal Agent Sch 38516,鈥 Z. Xu, C. W. Johannes, S. S. Salman, A. H. Hoveyda听.

24.听鈥淒iscovery of Chiral Catalysts through Ligand Diversity: Ti-Catalyzed Enantioselective Addition of TMSCN to听meso听Epoxides,鈥 B. M. Cole, K. D. Shimizu, C. A. Kruger, J. P. A. Harrity, M. L. Snapper, A. H. Hoveyda听.

23.听鈥淒irected Regioselective Ni-Catalyzed Alkylation and Hydride Addition of Allylic Ethers. A Remarkable Turnover in Regioselectivity,鈥 J. P. Morken, M. T. Didiuk, A. H. Hoveyda听.

22.听鈥淶irconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems,鈥 M. S. Visser, J. P. A. Harrity, A. H. Hoveyda听.

21.听鈥淐atalytic and Enantioselective Route to Medium-Ring Heterocycles. Asymmetric Zirconium-Catalyzed Ethylmagnesation of Seven- and Eight-Membered Rings,鈥 M. S. Visser, N. M. Heron, M. T. Didiuk, J. F. Sagal, A. H. Hoveyda听.

20.听鈥淗ighly Diastereoselective Hydrosilation Reactions. Spirocyclic Siloxanes: Sources of Si-Based Lewis Acids,鈥 D. G. J. Young, M. R. Hale, A. H. Hoveyda听.

19.听鈥淒irected Regio- and Stereoselective Nickel-Catalyzed Addition of Alkyl Grignard Reagents to Allylic Ethers,鈥 M. T. Didiuk, J. P. Morken, A. H. Hoveyda听.

18.听鈥淐ascade Catalysis in Synthesis. An Enantioselective Route to Sch 38516 (and Fluvirucin B1) Aglycon Macrolactam,鈥 A. F. Houri, Z. Xu, D. A. Cogan, A. H. Hoveyda听.

17.听鈥淓nantio-, Diastereo-, and Regioselective Zirconium-Catalyzed Carbomagnesation of Cyclic Ethers with Higher Alkyls of Magnesium. Utility in Synthesis and Mechanistic Implications,鈥 M. T. Didiuk, C. W. Johannes, J. P. Morken, A. H. Hoveyda听.

16.听鈥淶irconocene-Catalyzed Kinetic Resolution of Dihydrofurans,鈥 M. S. Visser, A. H. Hoveyda听.

15.听鈥淒iastereoselective Heteroatom-Directed Conjugate Addition of Silylcuprate Reagents to Unsaturated Carbonyls. A Stereoselective Route to 尾-Carbonyl Siloxanes,鈥 M. R. Hale, A. H. Hoveyda听.

14.听鈥淶irconium-Catalyzed Kinetic Resolution of Pyrans,鈥 J. P. Morken, M. T. Didiuk, M. S. Visser, A. H. Hoveyda听.

13.听鈥淶irconium-Catalyzed Asymmetric Carbomagnesation,鈥 J. P. Morken, M. T. Didiuk, A. H. Hoveyda听.

12.听鈥淩egio- and Stereoselective Carbon-Carbon Bond Formation through Transition Metal Catalysis. The Influence of Catalyst Chirality on Selective Ethylmagnesation of Chiral, Nonracemic Alcohols and Ethers,鈥 A. H. Hoveyda, J. P. Morken听.

11.听鈥淶irconium-Catalyzed Ethylmagnesation of Hydroxylated Terminal Alkenes; A Catalytic and Diastereoselective Carbon-Carbon Bond-Forming Reaction,鈥 A. F. Houri, M. T. Didiuk, Z. Xu, N. R. Horan, A. H. Hoveyda听.

10.听鈥淥n the Mechanism of the Zirconium-Catalyzed Carbomagnesation Reaction. Efficient and Selective Catalytic Carbomagnesation with Higher Alkyls of Magnesium,鈥 A. H. Hoveyda, J. P. Morken, A. F. Houri, Z. Xu听.

9.听鈥淩hodium (I)- and Iridium (I)-Catalyzed Hydroboration Reactions: Scope and Synthetic Applications,鈥 D. A. Evans, G. C. Fu, A. H. Hoveyda听.

8.听鈥淪iloxanes: Versatile Templates for Acyclic Stereocontrol. Synthesis of the C27-C33 Segment of Rapamycin,鈥 M. R. Hale, A. H. Hoveyda听.

7.听鈥淪tereoselective Zirconium-Catalyzed Ethylmagnesation of Homoallylic Alcohols and Ethers. The Influence of Internal Lewis Bases on Substrate Reactivity,鈥 A. H. Hoveyda, Z. Xu, J. P. Morken, A. F. Houri听.

6.听鈥淪tereoselective Formation of Carbon-Carbon Bonds Through Metal Catalysis. The Zirconium-Catalyzed Ethylmagnesation Reaction,鈥 A. H. Hoveyda, Z. Xu听.

5.听鈥淪amarium-Catalyzed Intramolecular Tishchenko Reduction of 尾-Hydroxy Ketones. A Stereoselective Approach to the Synthesis of Differentiated Anti 1,3-Diol Monoesters,鈥 D. A. Evans, A. H. Hoveyda听.

4.听鈥淩eduction of 尾-Hydroxy Ketones with Catecholborane. A Stereoselective Approach to the Synthesis of Syn-1,3-Diols,鈥 D. A. Evans, A. H. Hoveyda听.

3.听鈥淭he Rhodium(I)-Catalyzed Hydroboration of Olefins. The Documentation of Regio- and Stereochemical Control in Cyclic and Acyclic Systems,鈥 D. A. Evans, G. C. Fu, A. H. Hoveyda听.

2.听鈥淪ynthetic Studies of the Furan-Carbonyl Photocycloaddition Reaction. A Total Synthesis of (卤)-Avenaciolide,鈥 S. L. Schreiber, A. H. Hoveyda听.

1.听鈥淎 Photochemical Route to the Formation of Threo Aldols,鈥 S. L. Schreiber, A. H. Hoveyda, H-J. Wu听.

REVIEWS, PERSPECTIVES, CONCEPT ARTICLES

43.听鈥淭aking Olefin Metathesis to the Limit: Stereocontrolled Synthesis of Trisubstituted Alkenes,鈥澨鼳. H. Hoveyda, C. Qin, X. Z. Sui, Q. Liu, X. Li, A. Nikbakht听.

42.听鈥淐atalytic and Stereoselective Transformations with Easily Accessible and Purchasable Allyl and Alkenyl Fluorides,鈥澨齈. H. S. Paioti, S. A. Gonsales, S. Xu, A. Nikbakht, D. C. Fager, Q. Liu, A. H. Hoveyda听.

41.听鈥淚mpact of Ethylene on Efficiency and Stereocontrol in Olefin Metathesis: When to Add It, When to Remove It,and When to Avoid It,鈥澨鼳. H. Hoveyda, Z. Liu, C. Qin, T. Koengeter,听Y. Mu听.

40.听鈥淪ulfonate N-Heterocyclic Carbene鈥揅opper Complexes: Uniquely听Effective Catalysts for Enantioselective C鈥揅, C鈥揃, C鈥揌, and C鈥揝i Bond Formation,鈥澨鼳. H. Hoveyda, Y. Zhou, Y. Shi, K. Brown, H.听Wu, S. Torker听.

39.听鈥淐atalytic, Enantioselective, Copper鈥揃oryl Additions to Alkenes,鈥 A. H. Hoveyda, M. J. Koh, K. Lee, J. Lee, in听Organic Syntheses, S. E. Denmark, D. Hall, Eds;听2020, Vol 100, 959.

38.听鈥淒ifferent Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems,鈥 F. Romiti, J. del Pozo, P. H. S. Paioti, S. A. Gonsales, X. Li, F. W. W. Hartrampf, A. H. Hoveyda听.

37.听鈥淥rganoaluminum Compounds in Catalytic Enantioselective C鈥揅 Bond Forming Reactions,鈥 K. P. McGrath, A. H. Hoveyda in听The Chemistry of Organoaluminum Compounds., Z. Rappoport, I. Marek, Eds.; Wiley, Hoboken,听2017.

36.听鈥淎ctivation of B鈥揃 and B鈥揝i Bonds and Synthesis of Organoboron and Organosilicon Compounds through Lewis Base Catalyzed Transformations,鈥 A. Hoveyda, H. Wu, S. Radomkit, J. M. Garcia, F. Haeffner, K-S. Lee in听Lewis Base Catalysis; E. Vedejs, S. E. Denmark. Eds.; VCH-Wiley, Weinheim,听2016, Vol 3, 967.

35.听鈥淐atalyst-Controlled Stereoselective Olefin Metathesis,鈥 A. H. Hoveyda, R. K. M. Khan, S. Torker, S. J. Malcolmson, Handbook of Metathesis (Second Edition), R. H. Grubbs, D. J. O鈥橪eary, Eds.; VCH-Wiley, Weinheim,听2015, Vol 2, 503.

34.听鈥淓volution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity,鈥 A. H. Hoveyda听.

33.听鈥淒ichloro[[2-(1-methylethoxy-O)phenyl]- methylene](tricyclohexylphosphine) Ruthenium,鈥 S. B. Garber, A. H. Hoveyda, R. K. M. Khan, T. J. Mann,听

32.听鈥淐atalytic Enantioselective Olefin Metathesis and Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More,鈥 A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin听.

31.听鈥淐atalytic Enantioselective Olefin Metathesis and Natural Product Synthesis,鈥 A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin in听Metathesis in Natural Product Synthesis; Cossy, J. Ed.; Wiley-VCH,听2010, 343, (Chapter 12).

30.听鈥淐atalytic Enantioselective Olefin Metathesis,鈥 A. H. Hoveyda, S. J. Malcolmson, S. J. Meek, A. R. Zhugralin in听Catalytic Asymmetric Synthesis; Ojima, I. Ed.; Wiley-VCH,听2010, 739 (Chapter 8E).

29.听鈥淢olybdenum,[(S)-3,3鈥-bis(1,1-dimethylethyl)-5,5鈥,6,6鈥-tetramethyl[1,1鈥-biphenyl]-2,2鈥-diolato(2-)-kO,kO鈥橾-2-methyl-2-phenylpropylidene)[tricyclo[3.3.1.13,7]decan-1-aminato(2-)],鈥 S. J. Malcolmson, A. H. Hoveyda, R. R. Schrock, (Encyclopedia of Reagents for Organic Synthesis, Second Edition; Paquette, Crich, Fuchs, Molander, Eds.; 1765-1768); Wiley-VCH: Weinheim,2009.

28.听鈥淭he Remarkable Metal-catalysed Olefin Metathesis Reaction,鈥 A. H. Hoveyda, A. R. Zhugralin听.

27.听鈥淪mall Peptides as Ligands for Catalytic Asymmetric Alkylations of Olefins. Rational Design of Catalysts or of Searches that Lead to Them?,鈥 A. H. Hoveyda, A. W. Hird, M. A. Kacprzynski听.

26.听鈥淩u Complexes Bearing Bidentate Carbenes: From Innocent Curiosity to Uniquely Effective Catalysts for Olefin Metathesis,鈥 A. H. Hoveyda, D. G. Gillingham, J. J. Van Veldhuizen, O. Kataoka, S. B. Garber, J. S. Kingsbury, J. P. A. Harrity听.

25.听鈥淐ombinatorial Approaches,鈥 A. H. Hoveyda, K. E. Murphy in听Comprehensive Asymmetric Catalysis, Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer,听2004, 171 (Supplement to Chapter 39).

24.听鈥淢etathesis Reactions,鈥 A. H. Hoveyda, R. R. Schrock in听Comprehensive Asymmetric Catalysis, Supplement 1, E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer,听2004, 207 (Chapter 44).

23.听鈥淢olybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin-Metathesis Catalysts,鈥 R. R. Schrock, A. H. Hoveyda听.

22.听鈥淐atalytic Asymmetric Olefin Metathesis,鈥 A. H. Hoveyda, R. R. Schrock in听Handbook of Metathesis, R. H. Grubbs, Ed.; VCH-Wiley, Weinhein,听2003, 128 (Vol. 2).

21.听鈥淧olymer-Supported Olefin Metathesis Catalysts for Organic and Combinatorial Synthesis,鈥 J. S. Kingsbury and A. H. Hoveyda in听Polymeric Materials in Organic Synthesis and Catalysis, M. R. Buchmeiser, Ed.; VCH-Wiley, Weinheim,听2003, 467.

20.听鈥淐atalytic Asymmetric Olefin Metathesis,鈥 A. H. Hoveyda in听Organic Synthesis Highlights V, H-G. Schmalz and T. Wirth, Eds; VCH-Wiley, Weinheim,听2003, 210.

19.听鈥淐hiral Zirconium Catalysts for Enantioselective Synthesis鈥 A. H. Hoveyda in听The Chemistry of Titanium and Zirconium Complexes, I. Marek, Ed.; VCH-Wiley, New York,听2002, 180.

18.听鈥淒iversity-Based Approaches to Chiral Catalyst Discovery,鈥 A. H. Hoveyda in听The Handbook of Combinatorial Chemistry, K. C. Nicolaou, R. Hanko, W. Hartwig, Eds.; VCH-Wiley, Weinheim,听2002, 991.

17.听鈥淐atalytic Asymmetric Olefin Metathesis,鈥 A. H. Hoveyda, R. R. Schrock听<a href="https://doi.org/10.1002/1521-3765(20010302)7:53.0.CO;2-3鈥>Chem. Eur. J.2001,听7, 945.

16.听鈥淗igh-Throughput Screening of Titanium-Tripeptide Schiff Base Complexes for Catalytic Asymmetric Addition of Trimethylsilylcyanide to Epoxides and Imines,鈥 K. W. Kuntz, M. L. Snapper, A. H. Hoveyda in听High-Throughput Synthesis, Sucholeiki, I., Ed.; Marcel Dekker: New York,听2000, 283.

15.听鈥淐ombinatorial Approaches to Chiral Catalyst Discovery,鈥 M. L. Snapper and A. H. Hoveyda in听Combinatorial Chemistry,听Fenniri, H. Ed.; Oxford,听2000, 433.

14.听鈥淎symmetric Catalysis in Target-Oriented Synthesis,鈥 A. H. Hoveyda in听Stimulating Concepts in Chemistry, Stoddart, F. J., Shibasaki, M., Vogtle, F., Eds; VCH: Weinheim,听2000, 145.

13.听鈥淪tereoselective Addition of Grignard Reagents to Alkenes,鈥 A. H. Hoveyda, N. M. Heron, J. A. Adams in听Grignard Reagents: New Developments,听Richey, H. G., Ed.; John Wiley and Sons: New York,听2000, 107.

12.听鈥淐ombinatorial Catalysis: Identification of Potent Chiral Catalysts Through Fluorescent Bead Signaling,鈥 A. H. Hoveyda听.

11.听鈥淐arbometallation of Carbon-Carbon Double Bonds,鈥 A. H. Hoveyda, N. M. Heron in听Comprehensive Asmmetric Catalysis, Vol. III,听E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer-Verlag,听1999, 431.

10.听鈥淐ombinatorial Approaches,鈥 K. D. Shimizu, M. L. Snapper, A. H. Hoveyda in听Comprehensive Asmmetric Catalysis,听E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Eds.; Springer,听1999, 1389 (Chapter 39).

9.听鈥淐ombinatorial Catalyst Discovery,鈥 K. W. Kuntz, M. L. Snapper, A. H. Hoveyda听.

8.听鈥淢etal-Catalyzed Kinetic Resolution Processes,鈥 A. H. Hoveyda, M. T. Didiuk听Curr. Org. Chem.1998,听2, 489.

7.听鈥淗igh-Throughput Strategies for the Discovery of Catalysts,鈥 K. D. Shimizu, M. L. Snapper, A. H. Hoveyda听<a href="https://doi.org/10.1002/(SICI)1521-3765(19981002)4:103.0.CO;2-D鈥>Chem., Eur. J.1998,听4, 1885.

6.听鈥淐atalyst Discovery Through Combinatorial Chemistry,鈥 A. H. Hoveyda听.

5.听鈥淐atalytic Ring-Closing Metathesis and the Development of Enantioselective Processes,鈥 A. H. Hoveyda in听Metathesis, Furstner, A., Ed.; Springer: Berlin,听1998, 105.

4.听鈥淐hiral Titanocenes and Zirconocenes in Synthesis,鈥 A. H. Hoveyda and J. P. Morken in听Metallocenes, Togni, A.; Halterman R., Eds.; VCH: Weinheim;听1998,听Vol. 2, 625.

3.听鈥淐atalytic Enantioselective Addition of Grignard Reagents to Olefins,鈥 A. H. Hoveyda in听Transition Metals for Fine Chemicals and Organic Synthesis, Bolm, C. Ed.; VCH: Weinheim,听1998, 195.

2.听鈥淓nantioselective C-C and C-H Bond Formation Mediated or Catalyzed by Chiral ebthi Complexes of Titanium and Zirconium,鈥 A. H. Hoveyda, J. P. Morken听.

1.听鈥淪ubstrate-Directable Chemical Reactions,鈥 A. H. Hoveyda, D. A. Evans, G. C. Fu听.

Reviews, Perspectives, & Concept Articles

鈥淭aking Olefin Metathesis to the Limit: Stereocontrolled Synthesis of Trisubstituted Alkenes,鈥澨鼳. H. Hoveyda, C. Qin, X. Z. Sui, Q. Liu, X. Li, A. Nikbakht听

Non-Research Articles

  • 鈥淧rimo Levi鈥檚听The Periodic Table.听A Search for Patterns in Times Past,鈥 A. H. Hoveyda,听.
  • 鈥淪triving for Scientific Nirvana,鈥 A. H. Hoveyda,听Chemical & Engineering News听2001,听79, 198.

Patents

  • 鈥淪ynthesis of Z-Alkenyl Halides Through Stereoselective Olefin Methathesis,鈥 2017, Patent Number US 9,850,268.
  • 鈥淶-Selective Ring-Closing Metathesis Reactions,鈥 2017, Patent Number US 9,771,386.
  • 鈥淐atalysts for Efficient Z-Selective Metathesis,鈥 2017, Patent Number US 14,303,523.
  • 鈥淶-Selective Coupling of Terminal Olefins,鈥 2017, Patent Number US 9,713,808.
  • 鈥淯nique Chiral-at-Metal Catalysts for Remarkably Efficient and Exceptionally Enantioslecetive Olefin Metathesis,鈥 2017, Patent Number US 9,687,834.
  • 鈥淶-Selective Ring-Closing Metathesis Reactions,鈥 2016, Patent Number US 9,446,394.
  • 鈥淭ungsten Oxo Alkylidene Complexes for Z Selective Olefin Metathesis,鈥 2015, Patent Number US 9,085,595.
  • 听鈥淗igh Z-Selective Olefin Metathesis,鈥 2015, Patent Number US 9,079,173.
  • 鈥淪imple Organic Molecules as Catalysts for Practical and Enantioselective Synthesis of Amines and Alcohols,鈥 2015, Patent Number US 2015/0057451.
  • 鈥淓fficient Methods for Z鈥 or cis-Selective Cross-Metathesis,鈥 2013, Patent Number US 8,598,400.
  • 鈥淗ighly Z-Selective Olefin Metathesis,鈥 2013, Patent Number US 8,362,311.
  • 鈥淐omplexes for Use in Metathesis Reactions,鈥 2013, Patent Number US 8,546,500.
  • 听鈥淓fficient Methods for Z鈥 or cis-Selective Cross-Metathesis,鈥 2013, Patent Number US 8,552,242.
  • 听鈥淐atalysts and Processes for the Formation of Terminal Olefins by Ethenolysis,鈥 2012, Patent Number US 8,222,469.
  • 鈥淐atalysts for Metathesis Including Enantioselective Olefin Metathesis, And Related Methods,鈥 2009, Patent Number International WO 2009/094201.
  • 鈥淩ecyclable Metathesis Catalysts,鈥 2010, Patent Number US 7,723,255.
  • 鈥淩ecyclable Metathesis Catalysts,鈥 2005, Patent Number US 6,921,735.
  • 鈥淩ecyclable Chiral Metathesis Catalysts,鈥 2005, Patent Number US 6,939,982.
  • 鈥淐hiral Cyanoamines and Methods of Preparation,鈥 2004, Patent Number US 6,693,168.
  • 鈥淎symmetric Ring-Closing Metathesis Reactions Involving Achiral and Meso Substrates,鈥 2002, Patent Number US 6,346,652.